Critique Of Volume-Translated Equations of State: Empirical Approach and Physical Relevance

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They believe that finding these reasons will help them and others to develop reliable equations, and that these equations can be based on both theoretical and empirical methods. Being able to do this would go a long way toward helping researchers who are working with information involving the development of equations of state.
Another important finding of the article is the correlation between the values of virial coefficients that are involved in higher repulsion and the pole-packing fraction. The virial coefficients in question have improved values during a constant volume shift, whereas the second virial coefficient is lowered. Also of interest is that the curvature of the ln(Bi,rep) plot is not affected in either a positive of negative direction by this.
The main conclusion of the article being discussed was that empirical approaches are valuable, even though many seem to think that they are wrong. The authors strive to point out to their readers, and to others in ...

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